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When the natural spodumene is about 1100 °C, its crystals change from α type to β type, and at the same time, the volume expands and easily breaks into powder. Through grinding and screening producers, can achieve separation of spodumene and gangue minerals. (4) Heavy medium separation (HMS / DMS)

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Spodumene has been produced from all zones, although amblygonite occurs only in the intermediate zones and lepidolite only from cores zones. Spodumene was first produced at the Etta pegmatite in 1898 and sent to Omaha for experimentation. During the 1920's the Etta mine was the principal producer of lithium in the United States.

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